A Simple Method for the Biodiesel Production by the Reuse of Different Types of Waste Frying Oils

Tiago Almeida Silva, Antonio Carlos Ferreira Batista, Andressa Tironi Vieira, Marcelo Firmino de Oliveira

Abstract


A simple and complete method for the production and characterization of methylic and ethylic biodiesel from the main types of waste frying oils produced in Brazil was developed. The waste frying oils of soybean, canola, corn and sunflower were employed in the production of methylic and ethylic biodiesel by transesterification reaction via basic homogeneous catalysis. The transesterification reactions were performed at 40ºC during 40 min, using a catalyst percentage (KOH) equal to 2%. After separation of the phases biodiesel/glycerol, biodiesel was washed with 0.1M HCl aqueous solution, heated at 100 ºC to remove excess alcohol and finally filtered under vacuum with silica, a drying agent. The reaction yields were in the range 67.8-95.9%, quite satisfactory. The oxidative stability index was obtained for the oils as well as the biodiesel. Quality control of the original oil and of the methylic and ethylic biodiesels was accomplished by the TLC and GC-MS techniques. The results presented indicate the main waste frying oils produced in Brazil as potential sources of feedstocks for biodiesel production, which could aid in the development of the local cities that adopt programs to collect and reuse of waste oils. Furthermore, we emphasize that was obtained a route for biodiesel production greener, producing a biofuel substituent to mineral diesel by the reuse (or recycling) of waste.
Key words: Methylic biodiesel; Ethylic biodiesel; Waste frying oils

Keywords


Methylic biodiesel; Ethylic biodiesel; Waste frying oils

Full Text:

PDF

References


[1] Christopher, K., & Dimitrios, R. (2012). A Review on Exergy Comparison of Hydrogen Production Methods from Renewable Energy Sources. Energy & Environmental Science, 5, 6640-6651. Retrieved from http://dx.doi.org./10.1039/C2EE01098D

[2] BP Statistical Review of World Energy. (2012). Retrieved from http://www.bp.com/assets/bp_internet/globalbp/globalbp_uk_english/reports_and_publications/statistical_energy_review_2011/STAGING/local_assets/pdf/statistical_review_of_world_energy_full_report_2012.pdf

[3] Silva, T. A., Batista, A. C. F., & Vieira, A. T. (2012). A Brief Discussion of General Aspects of Biodiesel Production. Brazilian Geographical Journal: Geosciences and Humanities research medium, 3(1), 80-89. Retrieved from http://www.seer.ufu.br/index.php/braziliangeojournal/article/view/13961/ 9674

[4] Vyas, A. P., Verma, J. L., & Subrahmanyam, N. (2010). A Review on FAME Production Processes. Fuel, 89(1), 1-9. Retrieved from http://dx.doi.org/10.1016/j.fuel.2009.08.014

[5] Dresselhaus, M. S., & Thomas, I. L. (2001). Alternative Energy Technologies. Nature, 414, 332-337. Retrieved from http://dx.doi.org./10.1038/35104599

[6] Mekhilef, S., Siga, S., & Saidur, R. (2011). A Review on Palm Oil Biodiesel as a Source of Renewable Fuel. Renewable and Sustainable Energy Reviews, 15(4), 1937-1949. Retrieved from http://dx.doi.org/10.1016/j.rser.2010.12.012

[7] Koroneos, C., Spachos, T., & Moussiopoulos, N. (2003). Exergy Analysis of Renewable Energy Sources. Renewable Energy, 28(2), 295-310. Retrieved from http://dx.doi.org/10.1016/S0960-1481(01)00125-2

[8] Körbitz, W. (1999). Biodiesel Production in Europe and North America, an Encouraging Prospect. Renewable Energy, 16(10), 1078-1083. Retrieved from http://dx.doi.org/10.1016/S0960-1481(98)00406-6

[9] Oliveira, F. C. C., Suarez, P. A. Z., & Santos, W. L. P. (2007). Biodiesel: Possibilidades e Desafios. Química Nova na Escola, 28, 3-8. Retrieved from http://qnesc.sbq.org.br/online/qnesc28/02-QS-1707.pdf

[10] Leung, D. Y. C., Wu, X., & Leung, M. K. H. (2010). A Review on Biodiesel Production Using Catalyzed Transesterification. Applied Energy, 87(4), 1083-1095. Retrieved from http://dx.doi.org/10.1016/j.apenergy.2009.10.006

[11] Salvi, B. L., & Panwar, N. L. (2012). Biodiesel Resources and Production Technologies – A Review. Renewable and Sustainable Energy Reviews, 16(6), 3680-3689. Retrieved from http://dx.doi.org/10.1016/j.rser.2012.03.050

[12] Albuquerque, M. C. G., Machado, Y. L., Torres, A. E. B., Azevedo, D. C. S., Cavalcante Jr., C. L., Firmiano, L. R., & Parente Jr., E. J. S. (2009). Properties of Biodiesel Oils Formulated Using Different Biomass Sources and Their Blends. Renewable Energy, 34(3), 857-859. Retrieved from http://dx.doi.org/10.1016/j.renene.2008.07.006

[13] Rinaldi, R., Garcia, C., Marciniuk, L.L., Rossi, A.V., & Schuchardt, U. (2007). Synthesis of Biodiesel: a contextualized Experiment Proposal for the General Chemistry Laboratory. Química Nova, 30(5), 1374-1380. Retrieved from http://dx.doi.org/10.1590/S0100-40422007000500054

[14] Silva, N. L., Maciel, M. R. W., Batistella, C. B., & Filho, R. M. (2006). Optimization of Biodiesel Production from Castor Oil. Applied Biochemistry and Biotechnology, 129, 405-414. Retrieved from http://dx.doi.org/10.1007/9781597452687_33

[15] Zhang, Z., Dubé, M. A., McLean, D. D., & Kates, M. (2003). Biodiesel Production from Waste Cooking Oil: 1. Process Design and Technological Assessment. Bioresource Technology, 89(1), 1-16. Retrieved from http://dx.doi.org/10.1016/S0960-8524(03)00040-3

[16] Knothe, G. (2010). Biodiesel and Renewable Diesel: A Comparison. Progress in Energy and Combustion Science, 36(3), 364-373. Retrieved from http://dx.doi.org/10.1016/j.pecs.2009.11.004

[17] Chen, Y. H., Chen, J. H., Chang, C. Y., & Chang, C. C. (2010). Biodiesel Production from Tung (Vernicia Montana) Oil and Its Blending Properties in Different Fatty Acid Compositions. Bioresource Technology, 101(24), 9521-9526. Retrieved from http://dx.doi.org/10.1016/j.biortech.2010.06.117

[18] Conceição, M. M., Candeia, R. A., Silva, F. C., Bezerra, A. F., Fernandes Jr., V. J., & Souza, A. G. (2007). Thermoanalytical Characterization of Castor Oil Biodiesel. Renewable and Sustainable Energy Reviews, 11(5), 964-975. Retrieved from http://dx.doi.org/10.1016/j.rser.2005.10.001

[19] Sendzikiene, E., Makareviciene, V., & Janulis, P. (2006). Influence of Fuel Oxygen Content on Diesel Engine Exhaust Emissions. Renewable Energy, 31(15), 2505-2512. Retrieved from http://dx.doi.org/10.1016/j.renene.2005.11.010

[20] Morshed, M., Ferdous, K., Khan, M. R., Mazumder, M. S. I., Islam, M. A., & Uddin, Md.T. (2011). Rubber Seed Oil as a Potential Source for Biodiesel Production in Bangladesh. Fuel, 90(10), 2981-2986. Retrieved from http://dx.doi.org/10.1016/j.fuel.2011.05.020

[21] Lianhua, L., Pengmei, L., Wen, L., Zhongming, W., & Zhenhong, Y. (2010). Esterification of High FFA Tung Oil with Solid Acid Catalyst in Fixed Bed Reactor. Biomass and Bioenergy, 34(4), 496-499. Retrieved from http://dx.doi.org/10.1016/j.biombioe.2009.12.014

[22] Manh, D. V., Chen, Y. H., Chang, C. C., Chang, M. C., & Chang, C. Y. (2011). Biodiesel Production from Tung Oil and Blended Oil via Ultrasonic Transesterification Process. Journal of the Taiwan Institute of Chemical Engineers, 42(4), 640-644. Retrieved from http://dx.doi.org/10.1016/j.jtice.2010.11.010

[23] Silva T. A., & Batista, A. C. F. (2010). Production of Methylic and Ethylic Biodiesel from Peanut Oil Employing the Transesterification Reaction via Basic Homogeneous Catalysis. In: XVI Encontro Luso-Galego de Química, Aveiro, Portugal. Livro de Resumos do XVI Encontro Luso-Galego de Química, 234.

[24] Singh, S. P., & Singh, D. (2010). Biodiesel Production Through the Use of Different Sources and Characterization of Oils and Their Esters as the Substitute of Diesel: a Review. Renewable and Sustainable Energy Reviews, 14(1), 200-216. Retrieved from: http://dx.doi.org/10.1016/j.rser.2009.07.017

[25] Oliveira, M. F. O., Vieira, A. T. , Batista, A. C. F., Rodrigues, H. S., & Stradiotto, N. R. (2011). A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route. Journal of Biomedicine and Biotechnology, 2011, 1-4. Retrieved from http://dx.doi.org./10.1155/2011/238474

[26] Neto, P. R. C., Rossi, L. F. S., Zagonel, G. F., & Ramos, L. R. (2000). Production of Alternative Biofuel to Diesel Oil Through Transesterification of the Soybean Oil Used in Frying. Química Nova, 23(4), 531-537. Retrieved from http://dx.doi.org/10.1590/S0100-40422000000400017

27] EN 14112: 2003. (2003). Fat and Oil Derivatives–Fatty Acid Methyl Esters (FAME). Determination of Oxidation Stability (Accelerated Oxidation Test).

[28] Ferrari, R. A., & Souza, W. L. (2009). Evaluation of Oxidation Stability of Sunflower Oil Biodiesel with Antioxidants. Química Nova, 32(1), 106-111. Retrieved from http://dx.doi.org/10.1590/S0100-40422009000100020

[29] Jorge, N., Soares, B. B. P., Lunardi, V. M., & Malacrida, C. R. (2005). Physico-Chemical Alterations of Sunflower, Corn and Soybean Oils in Deep Fat Frying. Química Nova, 28(6), 947-951. Retrieved from http://dx.doi.org/10.1590/S0100-40422005000600003

[30] Haagenson, D. M., Brudvik, R. L., Lin, H., & Wiesenborn, D. P. (2010). Implementing an in Situ Alkaline Transesterification Method for Canola Biodiesel Quality Screening. Journal of the American Oil Chemists’ Society, 87(11), 1351-1358. Retrieved from http://dx.doi.org/10.1007/s11746-010-1607-9




DOI: http://dx.doi.org/10.3968/j.aped.1925543820130502.907

Refbacks

  • There are currently no refbacks.


Copyright (c)



Share us to:   

Reminder

  • How to do online submission to another Journal?
  • If you have already registered in Journal A, then how can you submit another article to Journal B? It takes two steps to make it happen:

1. Register yourself in Journal B as an Author

  • Find the journal you want to submit to in CATEGORIES, click on “VIEW JOURNAL”, “Online Submissions”, “GO TO LOGIN” and “Edit My Profile”. Check “Author” on the “Edit Profile” page, then “Save”.

2. Submission

  • Go to “User Home”, and click on “Author” under the name of Journal B. You may start a New Submission by clicking on “CLICK HERE”.

We only use three mailboxes as follows to deal with issues about paper acceptance, payment and submission of electronic versions of our journals to databases:
caooc@hotmail.com; aped@cscanada.net; aped@cscanada.org

 Articles published in Advances in Petroleum Exploration and Development are licensed under Creative Commons Attribution 4.0 (CC-BY). 

ADVANCES IN PETROLEUM EXPLORATION AND DEVELOPMENT Editorial Office

Address:1055 Rue Lucien-L'Allier, Unit #772, Montreal, QC H3G 3C4, Canada.

Telephone: 1-514-558 6138
Website: Http://www.cscanada.net
Http://www.cscanada.org
E-mail:office@cscanada.net;  office@cscanada.org

Copyright © 2010 Canadian Research & Development Centre of Sciences and Cultures