Review of Surfactant Enhanced Oil Recovery in Carbonate Reservoirs

James J. Sheng

Abstract


About half of proven conventional oil reserves are in carbonate reservoirs. Due to complex structures, formation heterogeneities and oil-wet/mixed wet conditions, etc., the oil recovery factor in carbonate reservoirs is very low. There is increasing interest in improve oil recovery using surfactants, as the surfactant EOR has the potential after other EOR methods have been tried.
This paper reviews the models of wettability alteration using surfactants and upscaling models related to oil recovery in carbonate reservoirs. Chemicals used in carbonate reservoirs are reviewed. The field cases where surfactants were used to stimulate oil recovery are analyzed.

Key words: Enhanced oil recovery; Carbonate reservoirs; Wettability alteration; Chemical EOR


Keywords


Enhanced oil recovery; Carbonate reservoirs; Wettability alteration; Chemical EOR

Full Text:

PDF

References


[1] International Energy Agency (IEA). (2006). Workd Energy Outlook 2006. Retrieved from http://www.worldenergyoutlook.org/media/weowebsite/2008-1994/WEO2006.pdf

[2] Schlumberger. (2007). Schlumberger Market Analysis. Retrieved from http://www.slb.com/~/media/Files/industry_challenges/carbonates/brochures/cb_carbonate_reservoirs_07os003.ashx

[3] BP. (2008). BP Statistical Review of World Energy, June. Retrieved from http://www.bp.com/liveassets/bp_internet/china/bpchina_english/STAGING/local_assets/downloads_pdfs/statistical_review_of_world_energy_full_review_2008.pdf

[4] Sheng, J. J. (2013). Comparison of the Effects of Wettability Alteration and IFT Reduction on Oil Recovery in Carbonate Reservoirs. Asia-Pacific Journal of Chemical Engineering, 8(1), 154–161.

[5] Delshad, M., Najafabadi, N. F., Anderson, G. A., Pope, G. A., & Sepehrnoori, K. (2009). Modeling Wettability Alteration by Surfactants in Naturally Fractured Reservoirs. SPE/DOE Symposium on Improved Oil Recovery, 22-26 April 2006, Tulsa, Oklahoma, USA.

[6] Leverett, M. C. (1941). Capillary Behavior in Porous Solids. Trans. AIME, 142, 152-169.

[7] UT Austin. (2009). A Three-Dimensional Chemical Flood Simulator (UTCHEM, version 9.95). Austin, Texas: University of Texas at Austin.

[8] Schlumberger. (2009). ECLIPSE Technical Manual.

[9] Adibhatla, B., Sun, X., & Mohanty, K. K. (2005). Numerical Studies of Oil Production from Initially Oil-Wet Fracture Blocks by Surfactant Brine Imbibitions. Paper SPE 97687 Presented at the SPE International Improved Oil Recovery Conference in Asia Pacific held in Kuala Lumpur, Malaysia, 5-6 December.

[10] Sheng, J. J. (2011). Modern Chemical Enhanced Oil Recovery – Theory and Practice. Burlington, MA: Elsevier.

[11] Delshad, M., Delshad, M., Bhuyan, D., Pope, G. A., & Lake, L. W. (1986). Effect of Capillary Number on the Residual Saturation of a Three-Phase Micellar Solution. Paper SPE 14911 Presented at the SPE Enhanced Oil Recovery Symposium, 20-23 April, Tulsa, Oklahoma.

[12] Fulcher Jr., R. A., Ertekin, T., & Stahl, C. D. (1985). Effect of Capillary Number and Its Constituents on Two-Phase Relative Permeability Curves. JPT, 37(2), 249-260.

[13] Anderson, W. G. (1987). Wettability Literature Survey part 5: The Effects of Wettability on Relative Permeability. JPT, 39(11), 1453-1468.

[14] Masalmesh, S. K. (2002). The Effect of Wettability on Saturation Functions and Impact on Carbonate Reservoirs in the Middle East. Paper 78515 Presented at the Abu Dhabi International Petroleum Exhibition and Conference, 13-16 October, Abu Dhabi, United Arab Emirates.

[15] Tang, G. Q., & Firoozabadi, A. (2002). Relative Permeability Modification in Gas/Liquid Systems through Wettability Alteration to Intermediate Gas Wetting. SPEREE, 5(6), 427-436.

[16] Mattax, C. C., & Kyte, J. R. (1962). Imbibition Oil Recovery from Fractured, Water-Drive Reservoir. SPE J, 2(2), 177-184.

[17] Kazemi, H., Gilman, J. R., & Elsharkawy, A. M. (1992). Analytical and Numerical Solution of Oil Recovery from Fractured Reservoirs with Empirical Transfer Functions. SPERE, 7(2), 219-227.

[18] Ma, S., Zhang, X., & Morrow, N. R. (1995). Influence of Fluid Viscosity on Mass Transfer Between Rock Matrix And Fractures. Paper Presented at the Annual Technical Meeting of the Canadian Society of Petroleum Engineers, 7-9 Jun, Calgary, Alberta, Canada.

[19] Zhang, X., Morrow, N. R., & Ma, S. (1996). Experimental Verification of a Modified Scaling Group for Spontaneous Imbibition. SPERE, 11(4), 280-286.

[20] Cuiec, L. E., Bourbiaux, B., & Kalaydjian, F. (1994). Oil Recovery by Imbibition in Low-Permeability Chalk. SPEFE, 9(3), 200-208.

[21] Li, K., & Horne, R. N. (2006). Generalized Scaling Approach for Spontaneous Imbibitions: an Analytical Model. Paper SPE 77544 Presented at the 2002 SPE Annual Technical Conference and Exhibition, San Antonio, TX, 29 September-2 October.

[22] Schechter, D. S., Zhou, D., & Orr Jr., F. M., (1994). Low IFT Drainage and Imbibitions. Journal of Petroleum Science and Engineering, 11, 283-300.

[23] Høgnesen, E. J., Standnes, D. C., & Austad, T. (2004). Scaling Spontaneous Imbibitions of Aqueous Surfactant Solution into Preferential Oil-Wet Carbonates. Energy & Fuels, 18, 1665-1675.

[24] Austad, T., & Standnes, D. C. (2003). Spontaneous Imbibition of Water into Oil-Wet Carbonates. J. Petroleum Science and Technology, 39, 363-376.

[25] Adibhatla, B., & Mohanty, K. K. (2008). Oil Recovery from Fractured Carbonates by Surfactant-Aided Gravity Drainage: Laboratory Experiments and Mechanistic Simulations. SPEREE (Feb.), 119-130.

[26] Standnes, D. C., & Austad, T. (2000). Wettability Alteration in Chalk 2. Mechanism for Wettability Alteration from Oil-Wet to Water-Wet Using Surfactants. Journal of Petroleum Science and Engineering, 28, 123–143.

[27] Hirasaki, G., & Zhang. D. L. (2004). Surface Chemistry of Oil Recovery from Fractured, Oil-Wet, Carbonate Formations. SPE J., 6, 151-162.

[28] Xie, X., Weiss, W. W., Tong, Z., & Morrow, N. R. (2005). Improved Oil Recovery from Carbonate Reservoirs by Chemical Stimulation, SPE J., 9, 276-285.

[29] Olson D. K., Hicks, M. D., Hurd, B. G., Sinnokrot, A. A., & Sweigart, C. N. (1990). Design of a Novel Flooding System for an Oil-Wet Central Texas Carbonate Reservoir. Paper SPE/DOE 20224 Presented at the SPE/DOE Seventh Symposium on Enhanced Oil Recovery held in Tulsa, OK, 22-25 April.

[30] Flaaten, A. K., Nguyen, Q. P., Zhang, J., Mohammadi, H., & Pope, G. A. (2010). Alkaline/Surfactant/Polymer Chemical Flooding Without the Need for Soft Water. SPE J., 15(1), 184-196.

[31] Standnes, D. C., & Austad, T. (2002). Wettability Alteration in Chalk 2. Mechanism for Wettability Alteration from Oil-Wet to Water-Wet Using Surfactants. Journal of Petroleum Science and Engineering, 28, 123-143.

[32] Tabatabal, A., Gonzalez, M. V., Harwell, J. H., & Scamehorn, J. F. (1993). Reducing Surfactant Adsorption in Carbonate Reservoirs. SPERE, 8(2), 117-122.

[33] Seethepalli, A., Adibhatla, B., & Mohanty, K. K. (2004). Physicochemical Interactions During Surfactant Flooding of Fractured Carbonate Reservoirs. SPE J., 12, 411-418.

[34] Chen, H. L., Lucas, L. R., Nogaret, L. A. D., Yang, H. D., & Kenyon, D. E. (2001). Laboratory Monitoring of Surfactant Imbibition with Computerized Tomography, SPEREE, 2, 16-25.

[35] Moritis, G. (2004). EOR Survey. Oil & Gas Journal, 53-65.

[36] Manrique, E. J., Muci, V. E., & Gurfinkel, M. E. (2007). EOR Field Experiences in Carbonate Reservoirs in the United States. SPEREE, 12, 667-686.

[37] Zubari, H. K., & Sivakumar, V. C. B. (2003). Single Well Tests to Determine the Efficiency of Alkaline-Surfactant Injection in a Highly Oil-Wet Limestone Reservoir. Paper SPE 81464 Presented at the Middle East Oil Show, 9-12 June, Bahrain.

[38] Yang, H. D., & Wadleigh, E. E. (2000). Dilute Surfactant IOR-Design Improvement for Massive, Fractured Carbonate Applications. Paper SPE 59009 Presented at the SPE International Petroleum Conference and Exhibition in Mexico, 1-3 February, Villahermosa, Mexico.

[39] Weiss, W. W., Xie, X., Weiss, J., Subramanium, V., Taylor, A., & Edens, F. (2006). Artificial Intelligence Used to Evaluate 23 Single-Well Surfactant-Soak Treatments. SPEREE, 6, 209-216.

[40] Rilian, N. A., Sumestry, M., & Wahyuningsih. (2010). Surfactant Stimulation to Increase Reserves in Carbonate Reservoir “A Case Study in Semoga Field”. Paper SPE 130060 Presented at the SPE EUROPEC/EAGE Annual Conference and Exhibition, 14-17 June, Barcelona, Spain.




DOI: http://dx.doi.org/10.3968/j.aped.1925543820130601.1582

Refbacks

  • There are currently no refbacks.


Copyright (c)




Share us to:   


Reminder

  • How to do online submission to another Journal?
  • If you have already registered in Journal A, then how can you submit another article to Journal B? It takes two steps to make it happen:

1. Register yourself in Journal B as an Author

  • Find the journal you want to submit to in CATEGORIES, click on “VIEW JOURNAL”, “Online Submissions”, “GO TO LOGIN” and “Edit My Profile”. Check “Author” on the “Edit Profile” page, then “Save”.

2. Submission

  • Go to “User Home”, and click on “Author” under the name of Journal B. You may start a New Submission by clicking on “CLICK HERE”.

We only use three mailboxes as follows to deal with issues about paper acceptance, payment and submission of electronic versions of our journals to databases:
caooc@hotmail.com; aped@cscanada.net; aped@cscanada.org

 Articles published in Advances in Petroleum Exploration and Development are licensed under Creative Commons Attribution 4.0 (CC-BY)

ADVANCES IN PETROLEUM EXPLORATION AND DEVELOPMENT Editorial Office

Address:1055 Rue Lucien-L'Allier, Unit #772, Montreal, QC H3G 3C4, Canada.

Telephone: 1-514-558 6138
Website: Http://www.cscanada.net
Http://www.cscanada.org
E-mail:office@cscanada.net;  office@cscanada.org

Copyright © 2010 Canadian Research & Development Centre of Sciences and Cultures